Thursday, April 2, 2009

HOT ICE

Sodium acetate is also used in consumer heating pads or hand warmers and is also used in “hot ice”. When sodium acetate trihydrate crystals (melting point 58 °C) are heated to around 100 °C, they melt. When this melt cools, it gives a supersaturated solution of sodium acetate in water. This solution is capable of supercooling to room temperature, well below its melting point, without forming crystals. By clicking on a metal disc in the heating pad, a nucleation center is formed which causes the solution to crystallize into solid sodium acetate trihydrate again. The bond-forming process of crystallization is exothermic, hence heat is emitted. The latent heat of fusion is about 264–289 kJ/kg (Source).

Is water is more acidic than ROH

yes water is more acidic than ROH becoz HO- is more stable than RO-
when nitrobenzaldehyde and methoxy benzaldehyde react together cannizaro reaction take place methoxy benzaldehyde give acid and other give alcohol